Kane will love this; the first game I ever bought for my PS1 was Batman and Robin
It was really hard, and the controls could be annoying, but I did enjoy playing it. I managed to finish it with some effort. The game was quite long. Set over the course of three days where you have to make it to different locations of Gotham at specific times, like to the museum to stop Mr. Freeze stealing the diamond, or to Police HQ to stop Ivy and Bane trashing the batsignal, before the crooks pull off their crime and get away.
I remember the game over cut scenes were pretty cool. There was one for Freeze and Ivy: