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True, she needs to be aware of a threat to deflect it.
However, she was able to deflect weapons that incapacitated , severely wounded and nearly killed Vision who is part Vibranium, (although clearly a lot less than many believed).
The same is true for Dr Strange. He's mortal, but capable of standing up to Thanos ( for a short time) much better than Hulk did at the start of IW. For all his durability he got flattened very quickly.
I don't think inherent durabilty should be the main determinant of a character's power tier.
Oh yeah, like you say, it isn't all. Many of the most powerful happen to be glass cannons because the highest tier powers often aren't related to strength or bodily powers which are going to have limited range. Mind powers for eg can affect every vulnerable being in a planet/universe - extreme telepathic or telekinetic powers like comics Phoenix, Xavier (Onslaught), Scarlet Witch etc and don't require a durable body to house those powers. But when you're doing aa analysis/comparison you'd note inherent durability as the base, then add on things you mention like deflection abilities (some heroes could be strong on both meaning double protection). Vision for eg can tank seriously heavy hits with his vibranium body but can also just go intangible or fly to avoid getting hit.

