Definitely. Their character interactions were electric on screen.
Okay this may be dumb, but how does Thor know about the Chitauri after Cap asks him what Loki's play is, Loki alludes to not being the mastermind and being shown the tesseracts true power but I still don't remember him mentioning the army in general or by name to Thor. Maybe I'm just that deaf (good thing I'm seeing it soon for a third time).
They never go into detail on how Thor knows. I'm just guessing Odin has informed Thor of what Loki's general plans are. Odin obviously knew something as he had to "gather all that dark energy" (as Loki stated) to get Thor back to Earth.
t
to get an empty theater.

