Buffy the Vampire Slayer/Angel:
Buffy Summers - Sarah Michelle Gellar/Along with Dana Scully, one of the first real female characters on television, also she's fairly awesome
Willow Rosenberg - Alyson Hannigan/Willow has a lot of traits that I also share and seeing those on TV is quite nice
Drusilla - Juliet Landau/I love Drusilla, she's one of my favorite physco characters ever. Juliet gave an otherwordly and creepy vibe but also let you feel pity for her.
Cordelia Chase - Charisma Carpenter/She's a lot of fun to watch
Dawn Summers - Michelle Trachtenberg/This may be an unpopular opinion but I quite like Dawn
Sherlock:
Mary Watson - Amanda Abbington/Abbington really impressed me in that she created a really wonderful, lived-in character from a description that was fairly formulaic.
Scandal:
Olivia Pope - Kerry Washington/Kerry just oozes power in the show and is an immensely capable actress that is fun to watch
Abby Whelan - Darby Stanchfield/I've loved Darby's character since the Pilot and as much as I like Olivia, I'm always a little sad that Abby has to take the backseat.
Mellie Grant - Bellamy Young/If Mellie were real I would hate her, but as a character on TV she's lots of fun to watch.
How to Get Away with Murder:
Annalise Keating - Viola Davis/I quite dislike Annalise but that is only because Davis gives it her all and makes her feel like a real person so everything terrible thing she does makes one dislike her more.
Agents of SHIELD:
Melinda May - Ming-Na Wen/She's badass and is over 50 and is gorgeous and is a well written character. What's not to love?
Jemma Simmons - Elizabeth Henstridge/Henstridge is a very good actress and I love the way she show's Simmons' interactions with the world.
Raina - Ruth Negga/Talented, manipulative, and smart, she is a character that is a lot of fun to watch.
Agent Carter:
Peggy Carter - Hayley Atwell/Simply Fantastic
Arrow:
Moira Queen - Susanna Thompson/Susanna Thompson was exceptional in playing a really layered character that could be powerful, week, and flawed.
X-Files:
Dana Scully - Gillian Anderson/Like Buffy she was a well-rounded character who paved the way for other great characters.