Going through my DVD collection;
Jackie Brown - Batman and Nick Fury.
Heat - Batman and Evey/Jane Foster
Universal Soldier series - Timecop, The Punisher, Spawn, Deadpool
Black Hawk Down - Hulk, Bane, Mr. Fantastic
Prometheus - Magneto, Heimdall, Aeon Flux, Aldritch Killian
Demolition Man - Judge Dredd, Blade
The Hurt Locker - Hawkeye, Falcon, Aldritch Killian
Confessions of a Dangerous Mind - Justin Hammer, Batman
Public Enemies - Batman, Talia, Deacon Frost, Dr Manhattan
RocknRolla - Bane, Heimdall, Sinestro and Carmine Falcone
Star Trek '09 - Hulk and Judge Dredd
Valkyrie - General Zod, Carmine Falcone and Eli Damaskinos,
The Tournament - Deadpool and Lady Deathstrike
American Gangster - Jor-El, Jonah Hex, Heimdall and Judge Rico
Troy - William Stryker, Hulk and Moira McTaggert
The Proposition - Aldritch Killian and William Stryker
The Assassination of Jesse James by the Coward Robert Ford - Hawkeye and Justin Hammer
Kill Bill - Poison Ivy and Nick Fury
Bad Lieutenant: Port of Call New Orleans - Ghost Rider and Batman
Munich - Hulk, Roarke and Lara Lor-Van
I'm tired and there's 400 other movies to get through!