In the Rhino's first appearance ASM # 41, Spidey just wore him down, constantly slamming Rhino head first into hard objects, finally flipping him head first into the pavement, knocking him unconscious.
In their second fight, working with Curt Connors Spidey developed an additive to his webbing that dissolved Rhino's synthetic hide.
One of my favorites has been the generator instances in the PS1 Spider-man game. Making him run into every one of them until he was literally weak in the knees and collapsed in front of Spidey.
Rhino's just really stupid, thats what makes him beatable. He's just a guy who charges at things mindlessly and uses no thought whatsoever.
There was an arc called "Flowers for a Rhino" where Rhino just his intelligence fixed or something, and quickly finds out Peter's identity and easily dominates him during their fights.
I just remember reading the Kingpin arc at the time it came out. Never got to read that story in particular.
But I do recall the beautifully painted covers for the Rhino arc with Spidey over him hanging from a tree and Rhino holding a flower smiling. That's an image I won't forget.
In the Ult. Spider-man game he fought him with the help of some quick drying cement, a wrecking ball and an open power source on the Rhino's back.
In the 90's cartoon I remember he used the symbiote costume to overpower him. This was also when he realised that the suit was amplifying his anger as well as strength as he stopped himself from splatting the Rhino with a very large steel door.
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