Hmm, as cool as it might be, Dr. Doom wouldn't have been my first villain solo flick choice.
Not that I'm riding the fanboy-bandwagon, but Venom would make a solid choice for a solo flick (maybe not with the current state of the Spidey franchise). In fact, all of the following fall less under the "Villain" category, and more under the Anti-Hero category.
I mean, Loki is a villain, but he is also a supporting character. Many care more about his plight than his brother's. Now THANOS. Now that's a solo flick I'd like to see. Similar in style to the Thanos Rising miniseries.
Although, that series made Thanos seem like a cosmic Dexter. Not necessarily perfect, but he's the perfect villain for it.
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