Completely agreed.
Oof, that's a tough ask. Like asking a parent to pick their favorite kid or something (except for the part where I was not involved at all in the production of the show).
In NO particular order:
- Natural Selection - Classic Parker luck; leave and Peter Parker is hated, stay and Lizard rampages freely. No pics? No money for bills, but if he sells them, he appears a traitor to his friends. The supporting cast was fantastic in this episode, especially Martha Connors.
- Shear Strength - Can't not have the Master Planner saga/Spider-Man lifts the rubble homage on my list. This whole 4-episode arc was great and Captain Stacy's character gets some shine. Big for Gwen's character IMO as well.
- Gangland - I adore the supporting cast of this show, and this may be the pinnacle of the high school gang's interactions. The Valentine's dinner at the restaurant is brilliantly-scripted, pushes multiple characters forward, develops new facets of characters we've known for almost 2 seasons now (Liz grows a spine, Mark protects his sister, Flash has a heart/isn't a big jerk at heart). The villains are awesome (especially Hammerhead), the setting is great, and Jonah really cracks me up in this one.
- Identity Crisis - Have I mentioned I love the supporting cast? They're treated well here, especially Flash--usually one of the most underrated, under-appreciated, under-utilized characters in the mythos really gets his chance to shine here. This isn't my favorite Venom episode, but the greater story pushes this up in spite of that.
- Final Curtain - This was a hard choice. I feel awful leaving off so many great S1 episodes, because I think I enjoy rewatching them more than a lot of S2, but this episode hits all the right marks. It sets the Goblin story right in an unprecedented way, creates even more intimate and personal stakes for Peter, and sets up the future of the show
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impeccably. It's a shame we never got to see what happens after this.
Honorable Mentions:
- Market Forces - Love Montana/Shocker on this show. This character just worked, and the juxtaposition of his idea of responsibility vs. Peter's great responsibility works perfectly. The fact that Peter actually ends up learning a lesson from Shocker and explaining himself to Aunt May by quoting his enemy at the end is the cherry on top. It sets up multiple plot points for the rest of the series, establishing character beats for Hammerhead (best use of the character in any media ever) and Norman Osborn.
- Group Therapy - Duh. What an awesome episode. Really demonstrates the ability of the writing team to weave together multiple stories from the classic, formative era of Spider-Man in a skillful and enjoyable way. Sometimes these changes can come across as offensive to fans, but on Spectacular they never did. Just the opposite, the changes made almost exclusively elevated the show.
- Catalysts - Probably my favorite episode not to make the "top 5" list. Excellent intro to the Green Goblin. I love his interaction with Tombstone's thugs, Tombstone's attempts to save his rep, Jonah and John's relationship, and nearly everything else. The ending, where Tombstone chides Peter for freely doing the job he was offered to be paid for, is classic Spider-Man--he can't win, for all the right reasons. The Fall Formal is great, MJ's character shines, and the dance between Peter and her at the end hits all the right beats.
Offhand, some of my favorite moments that aren't listed above are Mary Jane's introduction (and the constant "personality...ughh" joke that precedes it), pretty much anything involving Black Cat, Flash's mom embarrassing him at his party, Jonah yelling about stapling people to flagpoles, Spidey trapping Rhino on ice ("I hate you. So. Much."), all of Sandman (especially the sand castle scene), and so much more that I can't even remember right now.
Basically, this show is the best. In my opinion, it is the best portrayal of Spider-Man in any media outside of comics.