The Question said:Syndrome and Hades. Syndrome, because he actually had some depth to him, and Hades, because he actually had some personality. Most Disney villains are the same, menacing figure who never smiles and only laughs when it's some evil maniacle laugh. Hades was sarcastic, cynical, and had a serious temper. He was a bit quirkyer, but still plenty menacing. That's a good villain right there.