I feel like Uncle Scar from The Lion King should be on this list.
Surprised no one said Hans Landa. He's one of the best portrayals of a psychopath I've seen.
In alphabetical order:
Amon Goeth
Anton Chigurh
Darth Vader
Hannibal Lecter
Hans Landa
Michael Meyers
Norman Bates
Nurse Ratched
The Joker (Heath Ledger)
The Wicked Witch of the West
Tim Roth as Archibald Cunningham in Rob Roy was an excellent nasty baddie!
Ohh, good one Rowsdower! I was also thinking of Hammer Girl and Baseball Bat Man. They were great!
Also, speaking of underrated villains...
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