Ok here are some ways Spiderman can win the fight
First Way
*Spiderman goes up to Superman
Spider-Man: Hi, well I guess we might as well shake hands and may the best man win.
Superman: That is very honorable of you, and I want you to know that this is nothing personal and I will be as gentle as possible.
Spider-Man: That is very kind of you.
*They shake hands... Something pricks Supermans hand.
Superman: Owww.. What was that? What did you do to me?
Spider-Man: New powers, I call it my "Stinger"... I know it sounds silly, but as I said it is a new power and I have not come up with a better name for it. I thought of calling it my "Spider Claw" but that sounded stupid, besides there are a lot of people out there with claws and I wanted to stand out.
Superman: This is not possible, how can you hurt me with your stupid claws?
Spider-Man: No not claws, Stingers. As to how I can hurt you, they are magical in nature...
Superman: Ohhh I dont feel to good.
Spider-Man: That will be the venom coursing through your blood.
Superman: VENOM!!! You poisined me?
Super-Man: Dont worry you wont die.
Lois Lane: Stop talking to him and hit him before you fait.
Mary Jane: Hey shut up, no bench coaching.
Lois Lane: You shut up... *hits MJ
Mary Jane: You @%*&%... *Webs up Lois Lane
Lois Lane: Hey get this thing off me
Mary Jane: Oh shut up *Webs up Lois' mouth
Superman: Lois... *falls down and faints
Spider-Man: Wow, I won... Now lets get out of here before he wakes up, I dont think that trick will work twice on him.
Mary Jane: Wont he come looking for you?
Spider-Man: I will go by the Sentry and have him erase his memory of this event.
Mary Jane: While you are at it, have him do the same thing to his chick over there.
Spider-Man: Before we go, can you take a picture of me standing over Supermans fallen body? I mean no one is going to belive me when I tell them about what happened.
On the next episode, Spiderman defeates Superman using method number two....