It's ok man, don't freak. All is well.
For the basics on polymers, I'll give you this:
http://www.pslc.ws/macrog/kidsmac/wiap.htm
This is a solvent. It usually doesn't happen that quickly with other polymers It basically dissolves the polymer, but doesn't break the crosslinks.
http://www.youtube.com/watch?v=y2T8zayk6PM&feature=fvwrel
This is the type of adhesive we are working on:
http://en.wikipedia.org/wiki/Pressure_sensitive_adhesive
The polymers that are easily dissolved in acetone are:
styrofoam, cellulose acetate, and polycarbonate.
polyvinyl alcohol is easily dissolved in water.
We are attempting to build a new type of plastic.
a plastic= polymer + plasticizer+ additives.
the polymer gives it all the strength. We want a fiber that is at least 55 MPa strong.
the plasticizer gives the polymer flexibility. To find the plasticizer, we need to first choose a polymer, because they are rather specific.
The additives in our case are acetone and rubbers to create that adhesive.
The goal is to dissolve the plastic into a liquid with the consistency of syrup or honey. The plastic will then be extruded. When the extrusion hits the air, the acetone will evaporate. When the acetone evaporates, the liquid will have become a strong fiber with adhesive qualities. A good example of this is this video from 22:17-24:39
http://www.youtube.com/watch?v=QA0iv99VPvI
Now as for the web shooter itself, it's a tank of fluid like this:
http://www.youtube.com/watch?v=JAd9hwH2AP8
except, instead of a pump action, it's pressurized, and instead of a gun, there is a valve on the wrist. The fluid of course would be webbing. You can avoid the tank, but I prefer it or canisters that hook into the valve.
Finally, you could have the perfect web fluid, and the perfect shooter, but if you do not prepare it well, the fiber won't be worth anything. It needs to be drawn, extruded, or spun. The reason is because the molecules of the polymer get all screwy when it is dissolved. You need the fiber to be crystalline and elastomeric. This can only happen when it is put through a spinneret, dry spun, or electrospun.
That's the basic gyst. Once you learn this, and then study more, then you can create webbing and modify it and the shooter.