What specific scene/act by a villain would you consider the most evil?

I would say there is a significant distinction between acts that are most dangerous and/or a threat and acts that are most evil. Often they cross over but not always.
 
The Red Skull turning on Hitler was pretty dastardly. He basically busted a Starscream, LOL.
 
Deacon Frost for what was already mentioned, never realised he was such a badass :D

And Norman Osborn, or the Green Goblin that was possessing him, even after death he was able to cause damage
 

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