Thor wins. Next up:
US Agent(final form)
vs Spiderman(rookie)
Who you got peeps?
Depends - Spider Man and Walker may be comparable in theory, but due to different writers their actual abilities and competence vary wildly- especially Spider Man.
If this is in a show written by the FATWS crew then Spider Man wins easily - I mean after becoming a super soldier Walker should have been able to slaughter Karli and her mates singlehanded.
If it's Spider Man from Homecoming, then Walker wins because he was almost ****ing useless.
If it was the Russos, as in Civil War Spider Man, then probably Spider Man, although it would be a lot closer.
Rookie Spidey could only hang with Cap for a minute or two - and Cap was clearly not trying to hurt him badly. Walker might not be as restrained although unless Spider Man kills a friend of his in front of him, I doubt he's going to try to kill a teenage kid.
Given that super soldier serum reduces the difference in strength, durability and reaction time significantly - and Walker is a highly trained special forces soldier who's willing to kill if he has to......well.
So discounting the writers of Homecoming, Civil War and FATWS..... I'm going to say Spider Man,
but only just. While Walker's training compensates for some of their strength and speed differences Spider Man's tech gives him a couple of advantages that give him the edge.
I'll say Spidey 6/10, and Walker 4/10 - but I'm willing to change my mind.