I believe Superman would play along at first (probably thinking he'll just clear up any miss understanding of why he's being arrested) could he easily escape? yes
or at least assumes he can, but, doesn't want too hurt anyone
(until he realize something isn't right)
in this image here....
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Superman appears to be wearing a stunt rig rope/harness implying that maybe he does try to fly away at some point during this scene... and that's when they start to ruff him up a bit (and finds out he's equally matched by our mysterious man in black) who is able stop from doing soo
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theoretically of course